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Waste Polyolefins to Liquid Fuels via Pyrolysis: Review of Commercial State-of-the-Art and Recent Laboratory Research

机译:通过热解将聚烯烃废料转化为液体燃料:商业最新技术回顾和最新实验室研究

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摘要

With generation of waste plastics increasing, current EU legislation dictates high recovery rates and policy favours waste management technology choices that occupy a high position on the waste management hierarchy. Pyrolysis is a thermochemical conversion technology that can be considered a 'feedstock recycling' process and may play an increasing role in integrated waste management systems of the future. The objective of this article is to present a review of current state-of-the-art commercial pyrolysis processes for the production of liquid transport fuels from waste polyolefins (polyethylenes and polypropylenes). Current plastic waste generation and management practices are briefly summarised. Waste management infrastructure in Europe is reliant on landfill, incineration and mechanical recycling, while feedstock recycling plays an insignificant role. Plastic-to-liquid platforms including delocalised pyrolysis followed by centralised upgrading, stand alone facilities, and integrated waste management infrastructure concepts are briefly discussed. Commercial operations and their process configurations are compared. Reactor technology for cracking of plastic waste is presented. Important issues like fuel quality and contamination are also discussed. Fuel finishing operations and fuel additives required to achieve an engine ready fuel are described in the final section. Recently published laboratory research in thermal and catalytic pyrolysis and integrated and co-processing studies are also summarised in this review.
机译:随着废塑料产生量的增加,当前的欧盟法规要求回收率高,并且政策倾向于选择在废物管理体系中占据较高位置的废物管理技术选择。热解是一种热化学转化技术,可以被认为是“原料回收”过程,并且在未来的综合废物管理系统中可能扮演越来越重要的角色。本文的目的是介绍由废聚烯烃(聚乙烯和聚丙烯)生产液体运输燃料的当前最先进的商业热解工艺。简要总结了当前的塑料废物产生和管理实践。欧洲的废物管理基础设施依赖于垃圾掩埋,焚化和机械回收,而原料回收则起着微不足道的作用。简要讨论了塑料到液体的平台,包括离域热解,然后进行集中升级,独立的设施以及集成的废物管理基础架构概念。比较了商业运营及其流程配置。介绍了裂解塑料废料的反应器技术。还讨论了重要问题,例如燃料质量和污染。最后一节介绍了完成发动机可用燃料所需的燃料精加工操作和燃料添加剂。这篇综述还总结了最近发表的有关热和催化热解的实验室研究以及集成和共处理研究。

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